PALLADIUM-CATALYZED STEREOSELECTIVE CONSTRUCTION OF 1,3-STEREOCENTERS DISPLAYING AXIAL AND CENTRAL CHIRALITY VIA ASYMMETRIC ALKYLATIONS

Palladium-Catalyzed Stereoselective Construction of 1,3-Stereocenters Displaying Axial and Central Chirality via Asymmetric Alkylations

The concurrent construction of 1,3-stereocenters remains a challenge.Herein, we report the development of stereoselective union of a point chiral center with allenyl Wooden Toy axial chirality in 1,3-position by Pd-catalyzed asymmetric allenylic alkylation between racemic allenyl little boys shorts carbonates and indanone-derived β-ketoesters.Vari

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STRUCTURING THE NATO DEFENSE PLANNING PROCESS DURING THE COLD WAR

Even in the initial stages of NATO establishment, the way in which the necessary resources foe sustainment of the defence posture in front of Soviet threat was one of the most important topic.The complexity associated with this objective was even more challenging in the multinational context and common desire to reach an integrated character.From t

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